Host Paulino Duran leaves the beauty of Tuscany behind as he picks up his journey along the "Yellow Roads," the back roads of Italy to open this episode with a private performance at Posta de Donini Hotel. Then he drives to the capital of Umbria, the city of Perugia, the ancient banking capital in the high-walled city. From Perugia he heads to a private lunch in the middle of the vineyards in Lungarotti and enjoys a conversation with friends around fantastic wines. Leaving the wines behind, he visits the quaint town of Orvieto, with its magnificent Duomo, and lunch with his new friends at Franco's restaurant. From Orvieto he travels to Rome, where he spends time at the Duomo and The Trevi Fountain, along with a famous city expert. His journey ends at the Vatican with a private tour of the Vatican Museum, the Sistine Chapel and a dinner on the lawns of the Vatican.